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AMMONIUM PEROXODISULFATE

Ammonium persulfate

CAS: 7727-54-0

Molecular Formula: H8N2O8S2

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AMMONIUM PEROXODISULFATE - Names and Identifiers

Name Ammonium persulfate
Synonyms AP
APS
AMMONIUM PERSULFATE
Ammonium persulfate
Ammonium persulphate
AMMONIUM PEROXYDISULFATE
AMMONIUM PEROXODISULFATE
Ammonium peroxydisulfate
Ammonium peroxodisulfate
Ammonium peroxydisulphate
AMMONIUM PEROXYDISULPHATE
AMMONIUM PEROXODISULPHATE
diammonium peroxodisulphate
AMMONIUM PERSULFATE, POUCHES
[dioxybis(sulfonyloxy)]diammonium
diammonium dioxidan-2-idesulfonate
diammonium oxidooxysulfonyl sulfate
Ammonium persulfate Ammonium peroxodisulfate
diammonium [(sulfonatoperoxy)sulfonyl]oxidanide
Ammonium persulfate, Molecular Biology Grade Ammonium peroxodisulfate, Molecular Biology Grade
CAS 7727-54-0
EINECS 231-786-5
InChI InChI=1/2H3N.H2O5S/c;;1-5-6(2,3)4/h2*1H3;1H,(H,2,3,4)
InChIKey ROOXNKNUYICQNP-UHFFFAOYSA-N

AMMONIUM PEROXODISULFATE - Physico-chemical Properties

Molecular FormulaH8N2O8S2
Molar Mass228.2
Density1.98
Melting Point120 °C
Water Solubility582 g/L (20 ºC) decomposes
Solubility H2O: soluble
Vapor Presure0Pa at 25℃
Vapor Density7.9 (vs air)
Appearancepowder
Specific Gravity1.982
ColorWhite to yellow
OdorOdorless
Exposure LimitACGIH: TWA 0.1 mg/m3
Merck14,541
PH1.0-2.5 (25℃, 1M in H2O)
Storage ConditionStore at +15°C to +25°C.
StabilityStable. Oxidizing. May ignite combustible material. Incompatible with bases, combustible material, hydrogen peroxide, peroxy compounds, silver compounds, zinc. May decompose upon exposure to water
SensitiveMoisture Sensitive
Refractive Index1.50
Physical and Chemical PropertiesColorless monoclinic crystal or white crystalline powder.
The relative density is 1.982
The solubility is easily soluble in water, and the solubility is 58.2g/100ml water at 0 ℃.
UseUsed as food preservative, oxidant and initiator of high molecular polymer

AMMONIUM PEROXODISULFATE - Risk and Safety

Risk CodesR8 - Contact with combustible material may cause fire
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin.
R42/43 - May cause sensitization by inhalation and skin contact.
Safety DescriptionS22 - Do not breathe dust.
S24 - Avoid contact with skin.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37 - Wear suitable gloves.
UN IDsUN 1444 5.1/PG 3
WGK Germany1
RTECSSE0350000
TSCAYes
HS Code28334000
Hazard Class5.1
Packing GroupIII
ToxicityLD50 orally in rats: 820 mg/kg (Smyth)

AMMONIUM PEROXODISULFATE - Upstream Downstream Industry

Raw MaterialsAmmonia
Sulfuric acid
Ammonium sulfate
Downstream ProductsPotassium persulfate
Potassium persulfate
Ammonium persulfate
Sodium polyacrylate

AMMONIUM PEROXODISULFATE - Reference Information

pH range of acid-base indicator discoloration 1 - 2
LogP-1 at 20℃
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Overview ammonium persulfate is a white, tasteless single crystal with the molecular formula (NH4)2S2O8, which is highly oxidizing and corrosive, heat is easy to decompose, not easy to absorb moisture, soluble in water, increased solubility in warm water, in aqueous solution can be hydrolyzed into ammonium hydrogen sulfate and hydrogen peroxide. Its dry product has good stability, easy to store, and has the advantages of convenience and safety. It decomposes when heated to 120°C and is susceptible to moisture and agglomeration in humid air. It is mainly used as an oxidant and in the preparation of hydrogen peroxide, potassium persulfate and other persulfates. It can be used as a free initiator for polymer polymerization, especially emulsion polymerization and redox polymerization in the polymerization of vinyl chloride compounds. The grease, soap industry is used as a bleaching agent. For the preparation of aniline dyes and dyes oxidation and electroplating industry, photography and chemical analysis. Food grade used as a wheat modifier, beer yeast fungicide. It can also be used as Metal Etchants, circuit board cleaning and etching, copper and aluminum surface activation, starch modification, low temperature bleaching and Desizing of pulp and fabric, purification of circulating water system, oxidative degradation of harmful gases, low formaldehyde adhesive adhesion acceleration, disinfectant, hair dye decolorization, etc. Ammonium persulfate is non-flammable, but due to the release of oxygen and the role of combustion, the storage environment must be dry and clean, well ventilated. Pay attention to moisture and rain, rain is not suitable for transport. Should be kept away from fires, heat sources and direct sunlight. Keep the outer package sealed and the label intact and clear. It should be stored separately with flammable or combustible materials, organic matter, and reducing substances such as rust, a small amount of metal, etc., and should not be mixed to prevent the decomposition and explosion of ammonium persulfate.
toxicity is irritant and corrosive to skin and mucosa. After inhalation cause rhinitis, laryngitis, shortness of breath and Cough. Long-term skin contact can cause allergic dermatitis. Rat oral LD50 = 820mg/kg. GB 9685-2008 plastic ABS in the provisions of the maximum use of 0.2%; Adhesive and paper according to the production needs of the appropriate amount of use.
preparation method The refined electrolyte consists of high-level cells continuously entering the diaphragm cell, and the electrolyte consists: the cathode liquid is sulfuric acid 280 ~ 340kg/m3; Ammonium sulfate 180~210kg/m3. The anode liquid is sulfuric acid 110 ~ 140kg/m3; Ammonium sulfate 300~340/m3. In general, the current density of the anode is 20-25A/L, the cell voltage is 5.5-5.8V, and the electrolysis temperature is controlled at 25-30 °c. In order to improve the current efficiency, ammonium thiocyanate is usually added in an amount of about 0.015% to 0.03% of the electrolyte. After the electrolysis, the mass concentration of ammonium persulfate in the anode liquid should reach 220-260kg/m3, which is collected in the anode liquid storage tank, filtered into the crystallizer, and frozen under stirring to crystallize ammonium persulfate. When the temperature drops to -12 ℃ ~-8 ℃, stop freezing. Then centrifuged and dried to obtain the finished product. The reaction formula is as follows:(NH4)2SO4 + H2SO4(NH4)2S2O8 + H2
Use used as analytical reagent, photographic fixer and reducing agent
used as food preservative, oxidizing agent and initiator for high molecular polymer
The chemical industry is used as a raw material for producing persulfate and hydrogen peroxide, a polymerization promoter for organic polymer polymerization, and an initiator for polymerization of vinyl chloride monomer. The grease, soap industry is used as a bleaching agent. It is also used in the corrosion of metal plate cutting and oil production in the petroleum industry. Food grade used as a wheat modifier, beer yeast fungicide.
wheat flour modifier (limited ≤ 0.3g/kg, Japanese standard, 1999); Beer yeast fungicide (limited 0.1%,FAO/WHO,1984).
identification and determination of manganese, steel analysis, oxidants.
production method is obtained by crystallizing ammonium sulfate and dilute sulfuric acid after electrolysis.
The electrolysis method is made up of ammonium sulfate and sulfuric acid to form an electrolyte, and after removing impurities, electrolysis is carried out, HSO4-is discharged at the anode to generate peroxosulfuric acid, and then reacts with ammonium sulfate to generate ammonium persulfate, when the content of ammonium persulfate in the anode solution reaches a certain concentration, the ammonium persulfate product is prepared by filtration, crystallization, centrifugal separation and drying. Its anode reaction: 2HSO4 -- 2e → H2S2O8 cathode reaction: 2h2e → H2 (NH4)2S2O4 H2S2O8 →(NH4)2S2O8 H2SO4
category oxidant
toxicity grade poisoning
Acute toxicity oral-rat LD50: 689 mg/kg; Intraperitoneal-rat LD50: 226 mg/kg
explosive hazard characteristics strong oxidant; Can be mixed with reductant, sulfur, phosphorus, etc, open flame can be exploded
flammability hazard characteristics high thermal decomposition of oxygen; Toxic nitrogen oxides generated by heating, sulfur oxide and ammonia smoke
storage and transportation characteristics The warehouse is ventilated and dried at low temperature; Light loading and light unloading; With organic matter, reducing agent, sulfur, separate storage of phosphorus flammability
fire extinguishing agent water and sand mist
Occupational Standard TWA 2 mg/m3
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-05-06 10:48:01

AMMONIUM PEROXODISULFATE - Nature

Open Data Verified Data

colorless monoclinic crystal or white crystalline powder. Melting point 120 C (decomposition), 1_982 d. It has strong oxidation and corrosion. Completely dry ammonium persulfate is not easy to decompose, the wet ammonium persulfate will gradually decompose, release oxygen and ozone. Soluble in water, its aqueous solution will also decompose at room temperature. An explosive mixture can be formed by mixing with a reducing agent, an organic substance, a combustible substance, or a metal powder.

Last Update:2025-06-10 22:55:16

AMMONIUM PEROXODISULFATE - Preparation Method

Open Data Verified Data

an electrolytic solution was prepared from ammonium sulfate and sulfuric acid by an electrolysis method, and after removal of impurities, electrolysis was carried out. HS04 was discharged at the anode to generate peroxosulfuric acid, and then reacted with ammonium sulfate to obtain ammonium persulfate. When the content of ammonium persulfate in the anode solution reaches a certain concentration, it can be filtered, crystallized, centrifuged and dried.

Last Update:2025-06-10 22:55:16

AMMONIUM PEROXODISULFATE - Application

Open Data Verified Data

used as an initiator in the polymerization of tetrafluoroethylene. It is also an initiator for the polymerization or copolymerization of certain water-soluble monomers such as acrylic acid and its esters, acrylamide, vinyl acetate, and the like. Also useful as bleaching agents, deodorants, oxidizing agents, protein reagents and Analytical reagents for steel. It is also a raw material for the manufacture of persulfate and hydrogen peroxide.

Last Update:2025-08-19 16:24:40

AMMONIUM PEROXODISULFATE - Safety

Open Data Verified Data

rat oral LDso:820mg/kg. Combustion, corrosive, irritating, can cause human burns. Irritant and corrosive to the skin and mucous membranes. After inhalation cause rhinitis, laryngitis, shortness of breath and Cough. Eye and skin contact can cause intense irritation, pain and even Burns. Oral administration caused Abdominal Pain, Nausea and Vomit. Staff should be protected. If the skin and eyes are touched, they should be immediately rinsed with plenty of flowing water. Store in a cool, dry warehouse, away from fire, heat source. It is not allowed to mix with organic matter, reducing agent, flammable and explosive materials, storage and transportation.

Last Update:2025-06-10 22:55:16
AMMONIUM PEROXODISULFATE
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Mobile: +86-17551318830
Nantong Reform Petro-Chemical CO., LTD.
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AMMONIUM PEROXODISULFATE
MPD
ALPHA-PHENOXYPROPIONYL CHLORIDE
amobarbitone
HSDB 396
Keywords Dianthus extract
ALKYLARYLSULFONIC ACID
P-DIACETYLBENZENE
Raw Materials for AMMONIUM PEROXODISULFATE
Ammonia
Sulfuric acid
Ammonium sulfate
Downstream Products for AMMONIUM PEROXODISULFATE
Potassium persulfate
Potassium persulfate
Ammonium persulfate
Sodium polyacrylate
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